Bulgaria's independence from the Byzantine Empire has been restored due to a 1185 public riot in the city of Turnovo, which remained the capital of the Kingdom of Bulgaria intil the tragic 1393, when the Ottoman Turks took hold of it...
The third king in the row of the new dinasty, the Assenevtsi, was Tsar Kaloyan (ruled 1196-1207). In his attempt to re-establish his country, Kaloyan went into long and complicated negotiations with the Roman Pope Innocentius, whom he promissed a church unia with Rome on the condition of the Pope publically recognizing his Kings origin and the independence of the Bulgarian church. In 1204 a nuncio of Pope Innocent III crowned him King, and Kaloyan was presented with a scepter and a flag. Archbishop Vassily, the head of the Bulgarian church, was given the title of Primas.
However, Kaloyan preferred to style himself Emperor. Moreover, he was recognized as ruler not only of Bulgaria but of Vlachia, the lands north of the Danube, as well. Pope Innocent II himself wrote that "Kaloyan and his forerunners Peter and Assen have restored most of the country by right of their ancestors . The coronation amounted to a recognition of Bulgaria's independence, while ordinary Bulgarians maintained their Orthodox faith.
Kaloyan's diplomatic maneuvers temporarily averted the threat posed by the crusaders and strengthened the defence of the northwestern border where Catholic Hungarians still found it hard to put up with the loss of Belgrade and Branichevo. And most important of all, he gained time for preparation for the inevitable clash with the crusaders, already casting an eye on Thrace. He raised a strong army.
Meanwhile, negotiations were underway for an alliance with the Kumanians and the Seljuq Turks. The talks with Byzantine nobles provided further encouragement - Kaloyan was promised to be crowned in Constantinople as Byzantine Emperor in case he defeated the crusaders, an unprecedented promise in the history of Bulgarian-Byzantine relations.
Step by step Kaloyan was preparing for the victory that was finally won on 14 April 1205 near Adrianople. The Bulgarian shield clashed with the amour of the Latin knights, headed by Emperor Baldwin I Military historians have noted Kaloyan's skill in laying an ambush and, for the first time in Bulgarian history, the use ofreconnaissance in fight. They emphasize the excellent training of the Bulgarian troops and the perfect timing of the attack. The Bulgarian infantry and the Kumanian light cavalry routed the heavily armored knights, who had previously been considered invincible. "The cream of Latin chivalry was killed in that battle," wrote Robert de Claris. The emperor himself was captured and taken to Turnovo.
The battle of Adrianople, which revealed Kaloyan's exceptional talent as a military commander, echoed throughout Europe. The Latin empire was delivered a heavy blow and was to collapse several years later. In Rome the Pope had to give up his hopes of gaining control over the Eastern Orthodox Church. But it was not only fame Kaloyan fought for at Adrianople. His mind was focused on Bulgaria's survival next to the mighty Latin empire.
As a result of the victory Bulgaria became a force to be reckoned with. The fortresses of Seres, Skopje Ver and Muglen fell in succession. The following year the Bulgarians took Dimotica, Philipopolis, Cheraclea, Arcadiople and other strongholds. In the battle at Seres the Thessalonian King Bonifacius of Montferrat was killed.
The Bulgarians controlled almost the whole of Thrace, and Kaloyan often cast an eye on the walls of Constantinople. However, he knew that without a fleet, a siege of Constantinople would result in an immense loss.
(the information has been taken from Rulers of Bulgaria section of Bulgaria.com)